{Bis[2-(dicyclohexylphosphino)phenyl]methylsilyl-κ3 P,Si,P′}chloridoplatinum(II)
نویسندگان
چکیده
In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo-hexyl; cod = cyclo-octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo-hexane rings adopt a chair conformation.
منابع مشابه
{Bis[2-(dicyclohexylphosphino)phenyl]methylsilyl-κ3 P,Si,P′}chloridopalladium(II)
In the title compound, [Pd(C(37)H(55)P(2)Si)Cl], the Pd atom has a distorted square-planar geometry. The two five-membered rings adopt envelope conformations, while the four cyclo-hexane rings have chair conformations. The two planar aromatic rings are oriented at a dihedral angle of 28.79 (3)°.
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